CHARACTERISATION OF NANOFIBROUS SEPARATORS FOR LITHIUM-ION BATTERIES
Michal Musil
michal.musil@phd.feec.vutbr.czBrno University of Technology, Faculty of Electrical Engineering and Communication (Czechia)
David Pléha
Brno University of Technology, Faculty of Electrical Engineering and Communication (Czechia)
Abstract
Nano fibred materials ensure high porosity and relative surface area of separators. These parameters are important to improve ionic mobility between electrodes and ensure sufficient electrolyte volume in battery. These advantages make electrospinning very promising method of nanofibrous separators mass production. In this paper are described electrospinning fabrication process and discussed results of separator’s electric and electrochemical properties measurements compared with Celgard 3401.
Keywords:
spinning, battery, separator, impedance measurementReferences
Abraham K. M., Alamgir M., Hoffman D. K.: Polymer Electrolytes Reinforced by Celgard® Membranes. Journal of The Electrochemical Society 142/1995, 1347-1354.
Google Scholar
Cech O., Thomas J. E., Sedlarikova M., Fedorkova A., Vondrak J., Moreno M. S., Visintin A.: Performance improvement on LiFePO4/C composite cathode for lithium-ion batteries. Solid State Sciences 20/2013, 110-114.
Google Scholar
Cho T., Sakai T., Tanase S., Kimura K., Kondo Y., Tarao T., Tanaka M.: Electrochemical Performances of Polyacrylonitrile Nanofiber-Based Nonwoven Separator for Lithium-Ion Battery. Electrochemical and Solid-State Letters 10/2007, A159-A162.
Google Scholar
Ding B., Kim C., Kim H., Seo M., Park S.: Titanium dioxide nanofibers prepared by using electrospinning method. Fibers and Polymers 5/2004, 105-109.
Google Scholar
Duan B., Yuan X., Zhu Y., Zhang Y., Li X., Zhang Y., Yao K.: A nanofibrous composite membrane of PLGA–chitosan/PVA prepared by electrospinning. European Polymer Journal 42/2006, 2013-2022.
Google Scholar
Jung H., Ju D., Lee W., Zhang X., Kotek R.: Electrospun hydrophilic fumed silica/polyacrylonitrile nanofiber-based composite electrolyte membranes. Electrochimica Acta 54/2009, 3630-3637.
Google Scholar
Nanospider: Technologie electrospinningu. Elmarco. 2013, http://old.elmarco.com/obsah.php?id=27&s=2.
Google Scholar
Pleha D., Dvorak P., Kunovjanek M., Musil M., Cech O.: Battery Separators. ECS Trans. 2012 40(1)/2012, 153-155.
Google Scholar
Yang C., Jia Z., Guan Z., Wang L.: Polyvinylidene fluoride membrane by novel electrospinning system for separator of Li-ion batteries. Journal of Power Sources 189/2009, 716-720.
Google Scholar
Zhang S. S., Xu K., Jow T.R.: Electrochemical impedance study on the low temperature of Li-ion batteries. Electrochimica Acta. issue 7/2004, 1057-1061. DOI http://dx.doi.org/10.1016/j.electacta.2003.10.016.
Google Scholar
Zhao Z., Zheng J., Wang M., Zhang H., Han C.: High performance ultrafiltration membrane based on modified chitosan coating and electrospun nanofibrous PVDF scaffolds. Journal of Membrane Science 394395/2012, 209-217.
Google Scholar
Authors
Michal Musilmichal.musil@phd.feec.vutbr.cz
Brno University of Technology, Faculty of Electrical Engineering and Communication Czechia
Authors
David PléhaBrno University of Technology, Faculty of Electrical Engineering and Communication Czechia
Statistics
Abstract views: 151PDF downloads: 132
License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.