The influence of zeolites on hydration process of mineral binders
Jan Małolepszy
Department of Building Materials Technology; Faculty of Material Science and Ceramics; AGH University of Science and Technology (Poland)
https://orcid.org/0000-0002-7586-7851
Ewelina Grabowska
Department of Building Materials Technology; Faculty of Material Science and Ceramics; AGH University of Science and Technology (Poland)
Abstract
This paper presents the results of physical and chemical properties of zeolite - clinoptilolite (Z), on the basis of which its usefulness in different terms and applications was assessed. Same pozzolan was also investigated and analyzed in term of the changes that it causes in the system pozzolan - cement – lime - sand - water with different content of ingredients. In order to identify the hydration products in the natural conditions, infusion (80ºC) and autoclaving (180°C) XRD, DTA / TG and SEM was used. The results indicate that clinoptilolite is characterized by moderate pozzolanic activity and can be successfully used as a pozzolanic additive for cement, and a binder in the production of aerated concrete.
Keywords:
clinoptilolite, Ca(OH)2, pozzolanic activity, hydrothermal conditions, C-S-H, hydrogarnetsReferences
Tkaczewska E. Metody badań aktywności pucolanowej dodatków mineralnych, Materiały Ceramiczne, 63, 3, (2011), 536-541Burton T. Wind Energy. John Wiley & Sons, Ltd, 2001.
Google Scholar
Massazza F. Pozzolana and Pozzolanic Cement, Lea’s Chemistry of Cement and Concrete, Arnold, London, 1998, 471.
DOI: https://doi.org/10.1016/B978-075066256-7/50022-9
Google Scholar
Kosior-Kazberuk M., Nowe dodatki mineralne do betonu, Civil and Environmental Engineering / Budownictwo i Inżynieria Środowiska 2 (2011) 47-55.
Google Scholar
Stoleriu S.,Teoreanu I., Chemical and hardening processes in cementitious material - pozzolana - activator binding systems, International Conference of Building Materials, Weimar, 2009, P.154.
Google Scholar
Giergiczny Z., Rola popiołów lotnych wapniowych i krzemionkowych w kształtowaniu właścwiości współczesnych spoiw budowlanych i tworzyw cementowych, Wydawnictwo PK, Kraków 2006.
Google Scholar
Nocuń-Wczelik W., Pył krzemionkowy – podstawy stosowania w technologii betonu, Materiały Ceramiczne 2/2007, tom LIX.
Google Scholar
Wang H., Li H., Yan F., Synthesis and mechanical properties of metakaolinite-based geopolymer, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 268, Issues 1–3, (2005), 1-6.
Google Scholar
Gosh S.N. (ed.), Progress in Cement and Concrete. Cement and Concrete Science & Technology, ABI Books Privite Limited, Vol. 1, cz.1, 2, New Delhi 1991.
Google Scholar
Kurdowski W., Chemia cementu i betonu, Polski Cement, Warszawa, 2010.
Google Scholar
Skipkiūnas G., Sasnauskas V., Vaičiukynienė D., Daukšys M., Ivanauskas E., Hydration of cement paste with addition of modified zeolite, International Conference of Building Materials, Weimar, 2009, P.1.19
Google Scholar
Tokushige H., Kawakami M. and Bier T. A., Physical and mechanical properties of mortar and porous concrete using natural zeolite, International Conference of Building Materials, Weimar, 2009, P.2.07.
Google Scholar
Snellings R., Mertens G., Elsen J., Evaluation of the pozzolanic activity of natural zeolite tuffs, XIII ICCC International Congress On the Chemistry Of Cement, Madrid, 3-8 July, 2011, Area: 2, p.101.
Google Scholar
Handke M., Krzystalochemia krzemianów, UWND AGH, Kraków, 2008.
Google Scholar
Mertens G., Snellings R., Van Balen K., Bicer-Simsir B., Verlooy P., Elsen J. Pozzolanic reactions of common natural zeolites with lime and parameters affecting their reactivity, Cement and Concrete Research 39 (2009) 233-240.
DOI: https://doi.org/10.1016/j.cemconres.2008.11.008
Google Scholar
Ahmadi B., Shekarchi M. Use of natural zeolite as a supplementary cementitious material, Cement and Concrete Composites 32 (2010) 134-141.
DOI: https://doi.org/10.1016/j.cemconcomp.2009.10.006
Google Scholar
Grutzeck M., Kwan S., DiCola M. Zeolite formation in alkali-activated cementitious systems, Cement and Concrete Research 34 (2004) 949-955.
DOI: https://doi.org/10.1016/j.cemconres.2003.11.003
Google Scholar
Canpolat F., Yılmaz K., Köse M.M., Sümer M., Yurdusev M.A. Use of zeolite, coal bottom ash and fly ash as replacement materials in cement production, Cement and Concrete Research 34 (2004) 731-735.
DOI: https://doi.org/10.1016/S0008-8846(03)00063-2
Google Scholar
Król M., Mozgawa W., Pichór W., K.Barczyk Materiały autoklawizowane z zeolitu naturalnego, CWB-1/2013, 1-9.
Google Scholar
Arcoya A., González A., Travieso N., Seoane X.L. Physicochemical and catalytic properties of a modified natural clinoptilolite, Clay Minerals (1994) 29, 123-131.
DOI: https://doi.org/10.1180/claymin.1994.029.1.14
Google Scholar
Karakurt C., Kurama H., Topçu İ.B., Utilization of natural zeolite in areated concrete production, Cement and Concrete Composites 32 (2010) 1-8.
DOI: https://doi.org/10.1016/j.cemconcomp.2009.10.002
Google Scholar
Siemaszko-Lotkowska D., Gajewski R., Właściwości zeolitu w aspekcie zastosowania w betonie, Ceramika vol. 103, 2008.
Google Scholar
Bundyra-Oracz G., Siemaszko-Lotkowska D., Zeolit – dodatek pucolanowy do betonu, Budownictwo Technologie Architektura nr 4(52)/2010.
Google Scholar
Bogdanov B., Georgiev D., Angelova K., Yaneva K. Natural zeolites: clinoptilolite. Review, Natural&Mathematical science, Volume IV, s.6-11.
Google Scholar
http://www.lafarge.pl/Karta_produktowa_cementu_CEM_I_42_5_R.pdf
Google Scholar
http://www.trzuskawica.pl/wpcontent/uploads/2012/nowe/karty_produktow_wapnia/wapno%20hydra tyzowane%2017.08.2012..pdf
Google Scholar
Authors
Jan MałolepszyDepartment of Building Materials Technology; Faculty of Material Science and Ceramics; AGH University of Science and Technology Poland
https://orcid.org/0000-0002-7586-7851
Authors
Ewelina GrabowskaDepartment of Building Materials Technology; Faculty of Material Science and Ceramics; AGH University of Science and Technology Poland
Statistics
Abstract views: 242PDF downloads: 122
License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Budownictwo i Architektura supports the open science program. The journal enables Open Access to their publications. Everyone can view, download and forward articles, provided that the terms of the license are respected.
Publishing of articles is possible after submitting a signed statement on the transfer of a license to the Journal.