Influence of relative humidity and temperature on shell lime mortar with the addition of acacia gum and rice soup
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Abstract
Celem tego badania była ocena skuteczności organicznej zaprawy wapiennej zawierającej zupę ryżową i gumę arabską w trzech różnych regionach klimatycznych o różnych temperaturach i poziomach wilgotności: ciepłym i wilgotnym (35°C, 72%), suchym (25°C, 20%) i zimnym (25°C, 50%). Zupę ryżową i gumę arabską fermentowano przez jeden dzień, a następnie analizowano pod kątem składu fotochemicznego za pomocą chromatografii gazowej połączonej ze spektrometrią mas (GC-MS). Uwodnione fazy organicznych zapraw wapiennych badano za pomocą dyfrakcji rentgenowskiej (XRD), aby zrozumieć interakcje między wapnem a składnikami organicznymi. Skład fotochemiczny zupy ryżowej obejmował 62,35% alkanów i 10,14% nasyconych długołańcuchowych kwasów tłuszczowych, podczas gdy guma arabska zawierała 56,25% polisacharydów i 32,76% kwasów karboksylowych.Alkany w zupie ryżowej przyczyniły się do wzrostu wytrzymałości na ściskanie w próbce S2 (2,63 N/mm²), która była wyższa niż we wszystkich innych próbkach. Składniki mineralne w zupie ryżowej obejmowały kalcyt, portlandyt, albit, anortyt, aragonit, kwarc, C₃S₂H₃ (afwilit) i tobermoryt. Kwasy tłuszczowe reagowały z zaprawą wapienną, tworząc związki złożone; nastąpiła polimeryzacja, prowadząca do powstania CSH (hydratu krzemianu wapnia). Podobnie guma arabska zawierała kalcyt, albit, anortyt, kwarc, portlandyt i wateryt. Polisacharydy w gumie arabska przyczyniły się do poprawy karbonatyzacji. Podczas fermentacji kwasy karboksylowe redukowały CO₂, zwiększając karbonatyzację i prowadząc do powstania kalcytu, aragonitu i waterytu. Zupa ryżowa wykazała lepszą wydajność w ciepłym i wilgotnym klimacie ze względu na zwiększoną formację minerałów CSH; jednak nie nadawał się do suchych i zimnych warunków klimatycznych. Zaprawa z gumy akacjowej najlepiej sprawdzała się w suchych klimatach ze względu na swoje ulepszone właściwości mineralogiczne; jednak nie nadawała się do ciepłych, wilgotnych lub zimnych warunków klimatycznych.
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Thirumalini Selvaraj, CO2 Research & Green Technologies Centre; Vellore Institute of Technology;
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